Molecular quantum electrodynamics in chemical physics

Atomic Physics and Quantum Electrodynamics in the Infinite Momentum Frame*

.Over the past few years it has been shown that the use of an “infinite momentum’7 Lorentz frame1 has remarkable advantages for calculations in elementary particle physics and field theory, especially in the areas of current algebra sum rules, 2 parton models, 3, 4 and eikonal scattering.5,6 One important advantage is that it allows a straightforward application of the impulse and incoherence a...

Quantum anomaly in molecular physics.

The interaction of an electron with a polar molecule is shown to be the simplest realization of a quantum anomaly in a physical system. The existence of a critical dipole moment for electron capture and formation of anions, which has been confirmed experimentally and numerically, is derived. This phenomenon is a manifestation of the anomaly associated with quantum symmetry breaking of the class...

Calculation of Kolmogorov Entropy in Cavity Quantum Electrodynamics

In this paper Kolomogorov entropy of a simulated cavity quantum electrodynamics in a multi-partite system consisting of eight quantum dots in interaction with one cavity mode has been estimated. It has been shown that the Kolmogorov Entropy monotonically increases with the increasing coupling strength, which is a sufficient condition for chaotic behavior under ultrastrong coupling regime. The a...

Quantum Electrodynamics Effects in Rovibrational Spectra of Molecular Hydrogen.

The dissociation energies from all rovibrational levels of H2 and D2 in the ground electronic state are calculated with high accuracy by including relativistic and quantum electrodynamics (QED) effects in the nonadiabatic treatment of the nuclear motion. For D2, the obtained energies have theoretical uncertainties of 0.001 cm(-1). For H2, similar uncertainties are for the lowest levels, while f...

Quantum Electrodynamics in Graphene